Solution 1:
 Total forces on the piston
Weight of the piston acting downward=200N
Force due to Atmospheric pressure downward =100*103*20*10-4 N=200N
Let P be the Pressure of the gas
Then Force acting due to pressure of gas on the piston upward=PA
Force with the piston is being pulled upward=100N
Total Upward force=Total Downward force
PA + 100=200 +200
20*10-4*P=300
P=150kPa
Solution 2:
Since O2 is a diaatomic gas
CP=7R/2,CV=5R/2
Molecular mass=32 gm
Intial state 
Intial volume of gas
V=nRT/P
n=2*103/32
T=303K
R=8.3
P=500*103  N/m2
so V=.314  m3
Second state when At top volume  becomes double
Volume=2*.314 =.628m3
Pressure=500*103  N/m2 remains same
So as per ideal gas equation
T=606K
Workdone by the gas=PV=500*103*.314=157*103 J
Heat transfered=nCP(T2 -T1)
               =2*103 *7*8.3*303/32*2
               =550*103 J
Third state when Pressure becomes double
P=1000*103  N/m2
V=.628m3
As per ideal gas equation
Temperature=1212K
Heat transfered=nCV(T3 -T2)
                =2*103 *5*8.3*606/32*2
                 =785 kJ
So total heat tranfered=550+785=1335 kJ
Final Temperature=1216 K
Solution 3:
Since O2 is a diaatomic gas
CP=7R/2,CV=5R/2
Molecular mass=32 gm
Intial state
Intial volume of gas
V=nRT/P
n=1*103/32
T=303K
R=8.3
P0=500*103  N/m2
so V=.157  m3
Second state ( when piston reaches the spring)
v=.2 m3
P=500*103  N/m2
As per ideal gas equation
Temperature becomes=385.5 K
So heat tranfer till that point=nCP(T2 -T1)
                                =1*103 *7*8.3*82.5/32*2
                                =74.8 KJ
Third state ( when it compresses the spring)V=.2+0.1*0.25=0.225 m3
P=500*103 + kx/A
 =500*103 + 120*103*25*10-2/.1
  =800*103  N/m2
As per ideal equation 
Temperature becomes=694K
Change in Internal energy=nCV(T3 -T2)=5nR(T3 -T2)/2
                          =5*1*103*8.3*308.5/32*2
                          =200 KJ
Workdone by the gas =P0Ax + kx2/2
                    =500*103*.1*.25 + 120*103*.25*.25/2
                     =16.25 KJ
Total heat supplied in this Process=200+16.25=216.25KJ
So net Heat transfer=291.05 KJ
Solution 4:
Doubling the system should double the energy, so U is an extensive variable. 
Solution:5
By repeated application of the Zeroth Law, we can state that all M+N systems are in thermal equilibrium with each other. 
Solution:6
Total heat supplied =Workdone + Change in internal energy
So work done=2140-1580=560 J
Let s be the distance moved then
the  workdone is given by =Fs
Fs=560
s=560/F
 =560/102*10
s=.54 m
Solution:7
 As per dimension analysis Unit on both sides should be equal
      Now since R & R0 both unit are same
      Quantity 1+aT+bT5  should be dimension less
      so at should be dimension less
      so a unit is C-1
      similarly bt5 should be dimensionless
        so b unit is  C-5
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